Methyl 1-prop-2-yn-1-yl-1H-indole-5-carboxylate

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2-Methyl-3-{2-nitro-1-[2-(prop-2-yn-1-yl­oxy)phen­yl]eth­yl}-1H-indole

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In the title compound, C(11)H(8)BrNO(2), the nine-membered fused-ring is nearly planar [maximum deviation = 0.022 (2) Å] and the allyl group is arched over the nine-membered fused-ring at a dihedral angle of 89.2 (1)°. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal structure.

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In the title compound, C(10)H(11)ClN(4)O(2)S, the triazole ring carries methyl and ethoxy-carbonyl groups and is bound via a methyl-ene bridge to a chloro-thia-zole unit. There is also evidence for significant electron delocalization in the triazolyl system. Intra- and inter-molecular C-H⋯O hydrogen bonds together with strong π-π stacking inter-actions [centroid-centroid distance 3.620 (1) Å] s...

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ژورنال

عنوان ژورنال: Molbank

سال: 2007

ISSN: 1422-8599

DOI: 10.3390/m560